Abolfazl Heydari, Milad KhajeHassani, Haniyeh Daneshafruz, Sepideh Hamedi, Faeze Dorchei, Mário Kotlár, Fahimeh Kazeminava, Samahe Sadjadi, Farideh Doostan, Ivan Chodak, Hassan Sheibani
In: International Journal of Biological Macromolecules. Vol. 242, (2023)
https://doi.org/10.1016/j.ijbiomac.2023.124742
Abstract
This study presents the development and characterization of a nanocomposite material, consisting of thermoplastic starch (TPS) reinforced with bentonite clay (BC) and encapsulated with vitamin B2 (VB). The research is motivated by the potential of TPS as a renewable and biodegradable substitute for petroleum-based materials in the biopolymer industry. The effects of VB on the physicochemical properties of TPS/BC films, including mechanical and thermal properties, water uptake, and weight loss in water, were investigated. In addition, the surface morphology and chemical composition of the TPS samples were analyzed using high-resolution SEM microscopy and EDS, providing insight into the structure-property relationship of the nanocomposites. The results showed that the addition of VB significantly increased the tensile strength and Young’s modulus of TPS/BC films, with the highest values observed for nanocomposites containing 5 php of VB and 3 php of BC. Furthermore, the release of VB was controlled by the BC content, with higher BC content leading to lower VB release. These findings demonstrate the potential of TPS/BC/VB nanocomposites as environmentally friendly materials with improved mechanical properties and controlled release of VB, which can have significant applications in the biopolymer industry.