Autor Mária Čaplovičová

Influence of Nitrogen Pressure on the Adhesion and Scratch Failure Mechanisms of TiMoN/NbN Multilayer Coatings Deposited by Cathodic ARC PVD

Posted on by Mária Čaplovičová

O.V. Maksakova, V.M. Beresnev, S.V. Lytovchenko, M. Sahul, Mária Čaplovičová, R.S. Galushkov

In: East Eur. J. Phys., no. 1, pp. 540-547, Mar. 2026

https://doi.org/10.26565/2312-4334-2026-1-62

Abstract:

Multilayer nitride coatings are widely used to improve the mechanical performance and durability of engineering components subjected to severe tribological loading. In the present work, the adhesion behaviour and failure mechanisms of nanolayered TiMoN/NbN multilayer coatings deposited by cathodic arc PVD were investigated as a function of nitrogen working pressure. Two coatings were synthesized at nitrogen pressures of 0.52 Pa and 0.13 Pa under otherwise identical deposition conditions. Microscopy analysis revealed that both coatings exhibit a well-defined nanolayered architecture consisting of alternating TiMoN and NbN layers with a modulation period of approximately 85 nm and a total thickness of about 9.5 μm. The decreasing of nitrogen pressure results in a higher density of macroparticles due to the longer mean free path of cathodic arc plasma species. Scratch adhesion tests performed under progressive loading conditions allowed identification of two characteristic failure events corresponding to buckling crack initiation and buckling spallation. The multilayer coating deposited at 0.13 Pa demonstrated slightly improved resistance to crack initiation (5.41 N) compared with the multilayer coating deposited at 0.52 Pa (4.72 N). However, both coatings exhibited similar values of the second critical load (12.4–12.5 N). The multilayer coating deposited at higher nitrogen pressure mainly undergoes adhesive failure with extensive substrate exposure. In contrast, the multilayer coating deposited at lower nitrogen pressure exhibits predominantly cohesive damage within the multilayer structure. The obtained results demonstrate that nitrogen pressure during cathodic arc deposition significantly affects the microstructure evolution and the mechanisms of adhesion failure in TiMoN/NbN multilayer coatings. The study provides insight into the optimization of deposition parameters for improving the mechanical reliability of multilayer nitride coatings.

Advanced Biomaterials in Tissue Engineering Based on Antibacterial and Antibiofilm Nanocomposites for Multidrug-Resistant Wound Pathogens

Advanced Biomaterials in Tissue Engineering Based on Antibacterial and Antibiofilm Nanocomposites for Multidrug-Resistant Wound Pathogens

Posted on by Mária Čaplovičová

Aizhan B. Talipova, Volodymyr Buranych, Irina S. Savitskaya, Inara Abashidze, Fyodor I. Malchik, Dina H. Shokatayeva, Martin Sahul, Krzysztof Rokosz, Mária Čaplovičová, Alexander D. Pogrebnjak

In: ACS Omega 2026, 11, 9, 14806–14820

https://doi.org/10.1021/acsomega.5c11015

Abstract:

The treatment of chronic wounds is critically challenged by resilient biofilms formed by multidrug-resistant (MDR) pathogens, which are largely impervious to conventional antibiotics. This study addresses this challenge by engineering a multifunctional hydrogel dressing that synergistically integrates bacterial cellulose (BC), MXene nanosheets, and hydroxyapatite (HAp). Plays a critical dual role in the composite, significantly boosting bioactivity while also stabilizing the MXene to prevent oxidation and maintain its antibacterial properties. As a result, the BC/MXene/HAp composite achieved a near-total (98%) eradication of viable cells in mature biofilms of challenging MDR pathogens, including MRSA and FQRPA. Such activity is driven by a dual-mechanism that effectively disrupts both the initial attachment of bacteria and the structural scaffold of established biofilms. Complementing this efficacy, in vitro assays with NIH-3T3 fibroblasts confirm that the composite supports excellent cell adhesion, proliferation, and metabolic activity, highlighting its high biocompatibility. This work demonstrates a nonantibiotic strategy to combat biofilms through a synergistically designed biomaterial. Given its robust performance and multifunctionality, this platform is a promising candidate for the development of advanced therapeutic dressings in regenerative wound care.

Xenotime-(Gd), a new Gd-dominant mineral of the xenotime group from the Zimná Voda REE-U-Au quartz vein, Prakovce, Western Carpathians, Slovakia – CORRIGENDUM

Posted on by Mária Čaplovičová

Martin Ondrejka, Peter Bačík, Juraj Majzlan, Pavel Uher, Štefan Ferenc, Tomáš Mikuš, Martin Števko, Mária Čaplovičová, Stanislava Milovská, Alexandra Molnárová, Christiane Rößler and Christian Matthes

In: Mineralogical Magazine, 2026; 90(1) : 196-197

https://doi.org/10.1180/mgm.2025.10190

Core-shell nanofibers of ZnFe2O4/ZnO for enhanced visible-light photoelectrochemical performance

Posted on by Mária Čaplovičová

Andrii Lys, Viktor Zabolotnii, Mária Čaplovičová, Iryna Tepliakova, Agris Berzins, Martin Sahul, Ľubomír Čaplovič, Alexander Pogrebnjak, Igor Iatsunskyi, Roman Viter

In: Journal of Alloys and Compounds,Volume 984, 2024, 173885

https://doi.org/10.1016/j.jallcom.2024.173885

Abstract

Recent research places significant importance on the development of innovative nanocomposites for photoelectrochemical applications. This paper presents the fabrication, characterization, and possible photoelectrochemical applications of novel ZnFe2O4/ZnO core-shell nanofibers. These core-shell nanofibers were fabricated through co-axial electrospinning using PVP solutions containing iron and zinc nitrate precursors for the core and shell. The structural and optical properties of ZnFe2O4/ZnO core-shell nanofibers were examined through TEM, SEM, XRD, FTIR, Raman spectroscopy, and diffuse reflectance spectroscopy. This comprehensive analysis unveiled that the development of core and shell characteristics was notably influenced by the interdiffusion of [Fe]/[Zn] during the annealing process. The photoelectrochemical properties of ZnFe2O4/ZnO core-shell nanofibers were assessed through electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV), and the Mott-Schottky method. These core-shell nanofibers demonstrated a robust electrochemical response to visible light. Photocurrent and photoconversion efficiency of the core-shell nanofibers were calculated and compared with the corresponding values for core-shell nanoparticles. The mechanisms underlying the structural, optical, and photoelectrochemical properties of ZnFe2O4/ZnO core-shell nanofibers were discussed. These advanced nanofibers hold potential applications in photocatalysis, photovoltaics, and energy storage, making this research timely and crucial for advancing sustainable energy technologies and environmental remediation efforts.

Effect of bias voltage on the structural properties of WN/NbN nanolayer coatings deposited by cathodic-arc evaporation

Posted on by Mária Čaplovičová

K. Smyrnova, M. Sahul, M Haršáni, Ľ. Čaplovič, V. Beresnev, Mária Čaplovičová, M. Kusy and A. Pogrebnjak

In: J. Phys.: Conf. Ser. 2712 012014, 2024

https://doi.org/10.1088/1742-6596/2712/1/012014

Abstract

In this work, WN/NbN nanolaminate coatings were synthesized by cathodic-arc physical vapor deposition (CA-PVD) technique on a stainless-steel substrate. The paper reports the microstructure, cross-sectional morphology, surface roughness, and adhesion strength changes caused by variations in the absolute values of the negative substrate bias voltage, Us, in the 50-200 V range. Synthesized coatings were analyzed by Grazing incidence X-ray diffraction (GI-XRD), scanning transmission electron microscopy (STEM), scanning electron microscopy (SEM), laser scanning confocal microscopy (LSCM), and Daimler-Benz test. The phase analysis revealed that multilayer coatings had complex polycrystalline microstructure. They consisted of face-cantered cubic (fcc) β-W2N, fcc δ-NbN, and hexagonal ε-NbN phases. The total thickness and surface roughness had a descending trend with an increase in the absolute value of the negative bias voltage. Moreover, the WN/NbN coating deposited at Us = -50 V demonstrated the best adhesion strength to the substrate, suitable for protective coatings.

Influence of process and heat input on the microstructure and mechanical properties in wire arc additive manufacturing of hot work tool steels

Posted on by Mária Čaplovičová

Florian Pixner, Ricardo Buzolin, Fernando Warchomicka, Mária Dománková, Mária Čaplovičová, Florian Riedlsperger, Sebastian Fritsche, Marta Orłowska, Josef Domitner, Michael Lasnik, Norbert Enzinger

In: Materials Science and Engineering: A, Volume 888, 17 November 2023, 145799

https://doi.org/10.1016/j.msea.2023.145799

Abstract

The present study demonstrates the suitability of wire arc additive manufacturing (AM) for hot work tool steel processing. Different arc welding techniques and energy inputs were applied and systematically compared to determine the deposition characteristics, microstructure and mechanical properties. All AM deposits show a sound visual appearance and full density without macroscopic imperfections, i.e. cracking. By adhering to a pre-defined interpass strategy, the cold metal transfer process can be used to achieve higher weld beads with lower dilution and faster build-up rates than the metal active gas process. The microstructure of the AM parts is comparable for all process configurations and consists of an α/α′-matrix with a finely dispersed vermicular and polygonal δ-ferrite network; no notable amount of retained austenite could be measured, but it could be observed by transmission electron microscopy embedded within the laths. Intensive precipitation of multiple molybdenum-based precipitates is observed along the interface matrix to δ-ferrite. In contrast, iron-based precipitates are predominantly found inside and at the boundaries of the laths of the matrix. Similarities are also evident in the mechanical properties, resulting in an average hardness of 380–390 HV1 and absorbed impact energy of 10–12 J at room temperature. High yield strength values of 1000–1100 MPa and ultimate tensile strength of 1200–1400 MPa were obtained. No significant differences in the measured mechanical properties could be noted regarding the specimen orientation, indicating the isotropy of the properties.

Ag2O nanocrystals prepared by mechanochemical decomposition of Ag7O8NO3

Posted on by Mária Čaplovičová

Martin Škrátek, Mária Čaplovičová, Ľubomír Čaplovič, Patrícia Petrisková, Erik Šimon, Erik Rakovský, Peter Billik

In: Materials Letters. Vol. 348, (2023)

https://doi.org/10.1016/j.matlet.2023.134680

Abstract

Our work focuses on the preparation of nanocrystalline Ag2O (n-Ag2O) by mechanochemical decomposition (MCD) of a paramagnetic compound of an empirical formula Ag7O8NO3. Electrochemically prepared millimetre-long needles of Ag7O8NO3 were high-energy ball milled (HEM) for 1 min, 3 min and 5 min. A gradual decomposition of Ag7O8NO3 to n-Ag2O and AgNO3 was observed. Ag2O nanocrystals form in an aggregated and spherical morphology with crystallite sizes ranging from ∼10 – 30 nm. n-Ag2O displayed weak ferromagnetism with the saturation magnetisation of 5×10–3 emu/g. The MCD of Ag7O8NO3 can be estimated as follows: 2Ag7O8NO3 → 6Ag2O + 2AgNO3 + 5O2.

Application of MXene for remediation of low-level radioactive aqueous solutions contaminated with 133Ba and 137Cs

Posted on by Mária Čaplovičová

Vipul Vilas Kusumkar, Shalu Atri, Süleyman İnan, Maros Gregor, Tomas Roch, Hryhorii Makarov, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch and Olivier Monfort

In: Chem. Commun., 2023,59, 12007-12010

https://doi.org/10.1039/D3CC02147E

Abstract

MXene is an innovative multilayered material that has been prepared by an acid-salt (HCl + NH4F) etching route and tested for the removal of 133Ba and 137Cs in radioactive conditions for the first time. MXene has exhibited high uptake capacity of about 154.9 and 121.5 mg g−1 for 133Ba and 137Cs, respectively, in 0.01 mol L−1 solution and using 5 g L−1 of adsorbent at natural pH.

GaAs ablation with ultrashort laser pulses in ambient air and water environments

Posted on by Mária Čaplovičová

Edgaras Markauskas,  Laimis Zubauskas, Arnas Naujokaitis, Bronislovas Čechavičius, Martynas Talaikis, Gediminas Niaura, Mária Čaplovičová, Viliam Vretenár, Tadas Paulauskas

In: Journal of Applied Physics. Vol. 133, iss. 23 (2023)

https://doi.org/10.1063/5.0152173

Abstract

Water-assisted ultrashort laser pulse processing of semiconductor materials is a promising technique to diminish heat accumulation and improve process quality. In this study, we investigate femtosecond laser ablation of deep trenches in GaAs, an important optoelectronic material, using water and ambient air environments at different laser processing regimes. We perform a comprehensive analysis of ablated trenches, including surface morphological analysis, atomic-resolution transmission electron microscopy imaging, elemental mapping, photoluminescence, and Raman spectroscopy. The findings demonstrate that GaAs ablation efficiency is enhanced in a water environment while heat-accumulation-related damage is reduced. Raman spectroscopy reveals a decrease in the broad feature associated with amorphous GaAs surface layers during water-assisted laser processing, suggesting that a higher material quality in deep trenches can be achieved using a water environment.

Polycaprolactone–MXene Nanofibrous Scaffolds for Tissue Engineering

Posted on by Mária Čaplovičová

Kateryna Diedkova, Alexander D. Pogrebnjak, Sergiy Kyrylenko, Kateryna Smyrnova, Vladimir V. Buranich, Pawel Horodek, Pawel Zukowski, Tomasz N. Koltunowicz, Piotr Galaszkiewicz, Kristina Makashina, Vitaly Bondariev, Martin Sahul, Mária Čaplovičová, Yevheniia Husak, Wojciech Simka, Viktoriia Korniienko, Agnieszka Stolarczyk, Agata Blacha-Grzechnik, Vitalii Balitskyi, Veronika Zahorodna, Ivan Baginskiy, Una Riekstina, Oleksiy Gogotsi, Yury Gogotsi, and Maksym Pogorielov

In: ACS Applied Materials & Interfaces. Vol. 15, iss. 11 (2023)

https://doi.org/10.1021/acsami.2c22780

Abstract

New conductive materials for tissue engineering are needed for the development of regenerative strategies for nervous, muscular, and heart tissues. Polycaprolactone (PCL) is used to obtain biocompatible and biodegradable nanofiber scaffolds by electrospinning. MXenes, a large class of biocompatible 2D nanomaterials, can make polymer scaffolds conductive and hydrophilic. However, an understanding of how their physical properties affect potential biomedical applications is still lacking. We immobilized Ti3C2Tx MXene in several layers on the electrospun PCL membranes and used positron annihilation analysis combined with other techniques to elucidate the defect structure and porosity of nanofiber scaffolds. The polymer base was characterized by the presence of nanopores. The MXene surface layers had abundant vacancies at temperatures of 305–355 K, and a voltage resonance at 8 × 104 Hz with the relaxation time of 6.5 × 106 s was found in the 20–355 K temperature interval. The appearance of a long-lived component of the positron lifetime was observed, which was dependent on the annealing temperature. The study of conductivity of the composite scaffolds in a wide temperature range, including its inductive and capacity components, showed the possibility of the use of MXene-coated PCL membranes as conductive biomaterials. The electronic structure of MXene and the defects formed in its layers were correlated with the biological properties of the scaffolds in vitro and in bacterial adhesion tests. Double and triple MXene coatings formed an appropriate environment for cell attachment and proliferation with mild antibacterial effects. A combination of structural, chemical, electrical, and biological properties of the PCL–MXene composite demonstrated its advantage over the existing conductive scaffolds for tissue engineering.